Molecular structure and chirality (Author response)
نویسندگان
چکیده
منابع مشابه
Algebraic structure of central molecular chirality starting from Fischer projections.
The construction of algebraic structure of central molecular chirality is provided starting from the empirical Fischer projections for tetrahedrons. A matrix representation is given and the algebra of O(4) orthogonal group for rotations and inversions is identified. The result can be generalized to chains of connected tetrahedrons.
متن کاملPlasmonic polymers with strong chiroptical response for sensing molecular chirality.
We report on the chiroptical transfer and amplification effect observed in plasmonic polymers consisting of achiral gold nanorod monomers linked by cysteine chiral molecules in an end-to-end fashion. A new strategy for controlling the hot spots based circular dichroism (CD)-active sites in plasmonic polymers was developed to realize tailored and reproducible chiroptical activity in a controlled...
متن کاملMolecular Chirality and Chiral Parameters
Chirality permeates the entire fabric of the biological world. Indeed, life as we know it could not exist without chirality. The function of fundamental components of the cell, like actin, myosin, proteins, and lipids, relies upon their being chiral. The handedness of a molecule can affect its odor, potency, and toxicity. Thus the synthesis of a single enantiomer of a compound is crucial for th...
متن کاملControl of molecular chirality
We present a theoretical study of controlling molecular chirality in chemical reactions by circularly polarized fields. A theory of absolute asymmetric synthesis is formulated by standard perturbation theory. An estimation of the chiral polarization of the product is provided. We show that an unstable chiral configuration can be described as a spin one-half particle. The circularly polarized fi...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Chemical Education
سال: 1990
ISSN: 0021-9584,1938-1328
DOI: 10.1021/ed067p358.3